Front Cover: A Remarkable Ring Opening Observed in the Reaction of Cyclopropyl Ferrocenyl Thioketone with Triiron Dodecacarbonyl Fe <sub>3</sub> (CO) <sub>12</sub> (Eur. J. Inorg. Chem. 36/2022)
نویسندگان
چکیده
The Front Cover shows the radical-mediated ring opening process of a cyclopropyl group resulting in homoallyl radical, which is illustrated by blossoming flowering plant Cirsium arvense, typical at this time year some regions Europe. Based on proposed reaction mechanism, crucial and initial step ferrocenyl thioketone with triiron dodecacarbonyl (Fe3(CO)12) as Fe0 precursor, accompanied oxidation [Fe0] unit to [FeI]. In follow-up bifurcating cascade, leads two different iron carbonyl complexes ring-opened fragments, mononuclear η4-1-thia-1,3-diene-type species dinuclear η2-acyl-type compound. designed P. Buday. More information can be found Research Article G. Mlostoń, W. Weigand co-workers.
منابع مشابه
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2022
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202200722